Structural, optical, and electrical characteristics of HPMC/PVA-I2O5 composites: Fabrication and performance analysis for energy storage applications
DOI:
https://doi.org/10.1016/j.est.2024.112765الكلمات المفتاحية:
Olymers Composites ، HPMC/PVA I2O5 ، energy storageالملخص
تُستخدم مركبات البوليمر بشكل متزايد في تطبيقات تخزين الطاقة، لا سيما في المكثفات العازلة ، نظرًا لخصائصها المميزة ومزاياها مقارنةً بالإلكتروليتات السائلة التقليدية. في هذه الدراسة، بحثنا الخصائص البنيوية والبصرية والكهربائية والعازلة لأغشية مركبة من هيدروكسي بروبيل ميثيل سليلوز (HPMC) وبولي فينيل الكحول (PVA) مملوءة بتراكيز مختلفة من خماسي أكسيد اليود (I₂O₅ ) ، والمُحضّرة بطريقة الصبّ من المحلول. وقد أثّر دمج I₂O₅ في مصفوفة البوليمر بشكل ملحوظ على خصائص المركب. وكشفت تحليلات FTIR وXRD عن اضطرابات في البنية الجزيئية، وترتيب التبلور، ووجود أطوار بلورية من I₂O₅ في الأغشية المركبة. وأشارت حسابات نسبة التبلور إلى انخفاضها مع إضافة I₂O₅، مما أدى إلى زيادة محتوى الطور غير المتبلور، وهو ما يُحسّن التوصيل الكهربائي ( σ ) . وأظهرت دراسات مطيافية الأشعة فوق البنفسجية/ المرئية انخفاضًا في فجوات الطاقة البصرية، مما يُشير إلى تحسّن قدرة تخزين الشحنة. أظهر تحليل σ قيمًا مُحسّنة مع إضافة I₂O₅ ، مما يدل على تحسّن حركة الشحنات داخل الأغشية المركبة. وأبرزت السلوكيات المعتمدة على التردد في السماحية الكهربائية المعقدة ( ε ′ و ε ″) إمكانات هذه المركبات لتخزين الشحنات بكفاءة عبر نطاقات تردد مختلفة. وقدّم تحليل المعاوقة رؤىً حول الشحنات الفضائية والمسارات الموصلة داخل المركبات، مما يؤثر على خصائصها الكهربائية . وأظهرت المكثفات المصنعة من مركبات HPMC/PVA-I₂O₅ سعة تخزين طاقة مُحسّنة وخصائص توصيل مُتحكّم بها، مما يُشير إلى أداء واعد لتطبيقات تخزين الطاقة. تُبيّن نتائجنا أن مركبات HPMC/PVA-I₂O₅ تُعدّ مواد عازلة محتملة لتكنولوجيا المكثفات.
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