Structural, optical, and electrical characteristics of HPMC/PVA-I2O5 composites: Fabrication and performance analysis for energy storage applications

المؤلفون

  • Abdu Saeed جامعة ذمار image/svg+xml المؤلف
  • ZabnAllah M. Alaizeri جامعة الملك سعود image/svg+xml المؤلف
  • Saba A. Aladeemy جامعة سطام بن عبدالعزيز image/svg+xml المؤلف
  • Abeer Mohamed Alosaimi جامعة الطائف image/svg+xml المؤلف
  • Faisal Katib Alanazi جامعة الحدود الشمالية image/svg+xml المؤلف
  • Reem Alwafi جامعة الملك عبد العزيز image/svg+xml المؤلف
  • S.A. Alghamdi جامعة تبوك image/svg+xml المؤلف
  • Amal Mohsen Alghamdi جامعة الملك خالد image/svg+xml المؤلف
  • G.M. Asnag الجامعة الإماراتية الدولية image/svg+xml المؤلف

DOI:

https://doi.org/10.1016/j.est.2024.112765

الكلمات المفتاحية:

Olymers Composites ، HPMC/PVA I2O5 ، energy storage

الملخص

 تُستخدم  مركبات البوليمر بشكل متزايد في تطبيقات تخزين الطاقة، لا سيما في المكثفات العازلة  ، نظرًا لخصائصها المميزة ومزاياها مقارنةً بالإلكتروليتات السائلة التقليدية. في هذه الدراسة، بحثنا  الخصائص البنيوية والبصرية والكهربائية والعازلة لأغشية مركبة  من هيدروكسي بروبيل ميثيل سليلوز (HPMC) وبولي فينيل الكحول (PVA)  مملوءة  بتراكيز مختلفة من خماسي أكسيد اليود (I₂O₅ ) ، والمُحضّرة بطريقة الصبّ من المحلول. وقد أثّر دمج I₂O₅ في مصفوفة البوليمر بشكل ملحوظ على خصائص المركب. وكشفت تحليلات FTIR وXRD عن اضطرابات في البنية الجزيئية، وترتيب التبلور، ووجود أطوار بلورية من I₂O₅ في الأغشية المركبة. وأشارت حسابات نسبة التبلور إلى انخفاضها مع إضافة I₂O₅، مما أدى  إلى  زيادة  محتوى  الطور غير  المتبلور،  وهو  ما يُحسّن التوصيل الكهربائي ( σ  )  . وأظهرت  دراسات  مطيافية  الأشعة فوق البنفسجية/ المرئية انخفاضًا في فجوات الطاقة البصرية، مما يُشير إلى تحسّن قدرة تخزين الشحنة. أظهر تحليل σ قيمًا مُحسّنة مع إضافة I₂O₅ ،  مما  يدل على تحسّن  حركة الشحنات داخل الأغشية المركبة. وأبرزت السلوكيات المعتمدة على التردد في السماحية الكهربائية المعقدة ( ε ′ و  ε ″) إمكانات هذه المركبات لتخزين الشحنات بكفاءة عبر نطاقات تردد مختلفة. وقدّم تحليل المعاوقة رؤىً حول الشحنات الفضائية والمسارات الموصلة داخل المركبات، مما يؤثر على  خصائصها الكهربائية . وأظهرت المكثفات المصنعة من مركبات HPMC/PVA-I₂O₅ سعة تخزين طاقة مُحسّنة وخصائص توصيل مُتحكّم بها، مما يُشير إلى  أداء واعد لتطبيقات تخزين الطاقة. تُبيّن نتائجنا أن مركبات HPMC/PVA-I₂O₅ تُعدّ مواد عازلة  محتملة   لتكنولوجيا المكثفات.

السير الشخصية للمؤلفين

  • Abdu Saeed، جامعة ذمار
    Abdu Saeed Department of Physics, Thamar University, Thamar 87246, Yemen   Corresponding authors. Abdusaeed@tu.ed.ye Abdusaeed79@hotmail.com
  • ZabnAllah M. Alaizeri، جامعة الملك سعود
    ZabnAllah M. Alaizeri

    View in Scopus

    Department of Physics and Astronomy, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
  • Saba A. Aladeemy، جامعة سطام بن عبدالعزيز
    Saba A. Aladeemy

    View in Scopus

    Chemistry Department, College of Science and Humanities, Prince Sattam Bin Abdul-Aziz University, Al-Kharj 11942, Saudi Arabia
  • Abeer Mohamed Alosaimi، جامعة الطائف

    Abeer Mohamed Alosaimi

    Current affiliation: Taif University, Taif, Saudi Arabia Scopus ID: 57208905712
  • Faisal Katib Alanazi، جامعة الحدود الشمالية
    Faisal Katib Alanazi Department of Physics, Faculty of Sciences-Arar, Northern Border University, P.O. Box 1321, 91431 Arar, Saudi Arabia   Corresponding authors. Faisal.katib.al@gmail.com
  • Reem Alwafi، جامعة الملك عبد العزيز
    Reem Alwafi Department of Physics, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia
  • S.A. Alghamdi، جامعة تبوك
    S.A. Alghamdi Advanced Materials Research Laboratory, Department of Physics, Faculty of Science, University of Tabuk, Tabuk 71491, Saudi Arabia
  • Amal Mohsen Alghamdi، جامعة الملك خالد
    Amal Mohsen Alghamdi Physics Department, Faculty of Science, King Khalid University, Abha 61411, Saudi Arabia
  • G.M. Asnag، الجامعة الإماراتية الدولية

    G.M. Asnag

    Department of Biomedical Engineering, College of Engineering and Information Technology, Emirates International University, Sana'a 16881, Yemen   Correspondence to: G.M. Asnag, Department of Biomedical Engineering, College of Engineering and Information Technology, Emirates International University, Sana'a 16881, Yemen.

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Journal of Energy Storage

التنزيلات

منشور

2024-06-23

إصدار

القسم

Articles

الفئات

كيفية الاقتباس

Saeed, A., Alaizeri, Z. M. ., Aladeemy, S. A. ., Alosaimi, A. M. ., Alanazi, F. K. ., Alwafi, R. ., Alghamdi, S. ., Alghamdi, A. M. ., & Asnag, G. . (2024). Structural, optical, and electrical characteristics of HPMC/PVA-I2O5 composites: Fabrication and performance analysis for energy storage applications. المستودع الرقمي الجامعة الإماراتية الدولية, 1(1), 1-11. https://doi.org/10.1016/j.est.2024.112765

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