Enhanced linear and nonlinear optical properties of poly(vinyl alcohol) films with manganese(III) tetraphenylporphyrin chloride additive for optoelectronic applications

المؤلفون

  • Ali A Al-Muntaser Department of Physics, Faculty of Education and Applied Sciences at Arhab, Sana'a University, Sana'a, Yemen المؤلف
  • Eman Alzahrani Department of Chemistry, College of Science, Taif University, Taif, Saudi Arabia المؤلف
  • FA Al-Marhaby Department of Physics, Al-Qunfudhah University College, Umm Al-Qura University, Makkah, Saudi Arabia المؤلف
  • Zainab M Alharbi Department of Physics, College of Science and Art in Rabigh, King Abdulaziz University, Rabigh, Saudi Arabia المؤلف
  • Turki Alkathiri Department of Electrical Engineering, College of Engineering, Al-Baha University, Albaha, Saudi Arabia المؤلف
  • Sultan Albarakati Departmentof Physics, College of Science, University of Jeddah, Jeddah, Saudi Arabia المؤلف
  • Saleh A Alghamdi Advanced Materials Research Laboratory, Department of Physics, Faculty of Science, University of Tabuk, Tabuk, Saudi Arabia المؤلف
  • Ghaleb M Asnag الجامعة الإماراتية الدولية image/svg+xml المؤلف
  • Abdu Saeed Nuclear Engineering Department, Faculty of Engineering, King Abdulaziz University, Jeddah, Saudi Arabia المؤلف https://orcid.org/0000-0002-8506-7188

DOI:

https://doi.org/10.1002/pi.70049

الكلمات المفتاحية:

PVA composite films، MnTPPCl additive، optical bandgap; nonlinear optical properties ;ATR-FTIR spectroscopy; optical conductivity

الملخص

Polymer-based composite materials with tunable optical properties have garnered significant attention due to their potential applications in optoelectronics and photonics. Among them, poly(vinyl alcohol) (PVA) has been extensively investigated owing to its excellent film-forming ability, optical transparency and compatibility with functional additives. In this study, composite films were fabricated by incorporating manganese(III) tetraphenylporphyrin chloride (MnTPPCl: a metalloporphyrin complex that absorbs visible light) into a PVA matrix at concentrations of 0.05, 0.1 and 0.25 wt% via the conventional solution casting method. The films were characterized using attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, SEM and UV–visible–near infrared (NIR) spectrophotometry to examine their structural, morphological and optical properties, respectively. ATR-FTIR analysis confirmed the successful formation of molecular interactions between MnTPPCl and PVA, facilitated by hydrogen bonding and coordination. SEM micrographs revealed a smooth surface for pure PVA, whereas the incorporation of MnTPPCl introduced uniformly distributed spherical domains whose size and density increased with the dopant concentration. Optical studies revealed a redshift in the absorption edge, accompanied by the emergence of MnTPPCl-specific absorption bands. A decrease in the indirect optical bandgap (from 4.98 to 4.37 eV) and an increase in the absorption coefficient (up to 10−13 cm−1) were observed. Furthermore, enhancements in both optical conductivity and dielectric response were recorded. Nonlinear optical measurements demonstrated a pronounced improvement, with the third-order nonlinear susceptibility (χ(3)) increasing from 1 × 10−13 to 1.2 × 10−13 esu, and the nonlinear refractive index (n2) exhibiting a tenfold enhancement. These results demonstrate that MnTPPCl can effectively tune the structural and optical properties of PVA, making these composites promising materials for advanced optoelectronic, nonlinear optical and photonic device applications. © 2025 Society of Chemical Industry.

 

السير الشخصية للمؤلفين

  • Ali A Al-Muntaser، Department of Physics, Faculty of Education and Applied Sciences at Arhab, Sana'a University, Sana'a, Yemen

    Department of Physics, Faculty of Education and Applied Sciences at Arhab, Sana'a University, Sana'a, Yemen

    Correspondence to: AA Al-Muntaser, Department of Physics, Faculty of Education and Applied Sciences at Arhab, Sana'a University, Sana'a, Yemen, E-mail: almuntser2015@gmail.com, ali.almuntasser@su.edu.ye; or E Alzahrani, Department of Chemistry, College of Science, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia. E-mail: e.mohsan@tu.edu.sa

  • Eman Alzahrani، Department of Chemistry, College of Science, Taif University, Taif, Saudi Arabia

    Department of Chemistry, College of Science, Taif University, Taif, Saudi Arabia

    Correspondence to: AA Al-Muntaser, Department of Physics, Faculty of Education and Applied Sciences at Arhab, Sana'a University, Sana'a, Yemen, E-mail: almuntser2015@gmail.com, ali.almuntasser@su.edu.ye; or E Alzahrani, Department of Chemistry, College of Science, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia. E-mail: e.mohsan@tu.edu.sa

  • Ghaleb M Asnag، الجامعة الإماراتية الدولية

    Ghaleb M Asnag

  • Abdu Saeed، Nuclear Engineering Department, Faculty of Engineering, King Abdulaziz University, Jeddah, Saudi Arabia

    Abdu Saeed

    Nuclear Engineering Department, Faculty of Engineering, King Abdulaziz University, Jeddah, Saudi Arabia

    K.A.CARE Energy Research and Innovation Center, King Abdulaziz University, Jeddah, Saudi Arabia

    Physics Department, Thamar University, Thamar, Yemen

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التنزيلات

منشور

2025-11-05

إصدار

2025

القسم

Articles

الفئات

كيفية الاقتباس

Al-Muntaser, A. A., Alzahrani, E., Al-Marhaby, F., Alharbi, Z. M., Alkathiri, T., Albarakati, S., Alghamdi, S. A., Asnag, G. M., & Saeed, A. (2025). Enhanced linear and nonlinear optical properties of poly(vinyl alcohol) films with manganese(III) tetraphenylporphyrin chloride additive for optoelectronic applications. المستودع الرقمي الجامعة الإماراتية الدولية, 1(1). https://doi.org/10.1002/pi.70049

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