α-MoO3 Nanobelts Boosted the Structural, Optical, Thermal, and Dielectric Properties of PEO/PVP Blends for Emerging Optoelectronic/Energy-Storage Applications

المؤلفون

  • Eman M. Abdallah Department of Basic Sciences. Delta University for Science and Technology, Gamesa. Mansoura. Egypt المؤلف
  • Maha Aiiad Alenizi Department of Physics. Faculty of Sciences-Arar. Northern Border University, P.O. Box 1321 , 91431 Arar. Saudi Arabia المؤلف
  • Ghaleb M. Asnag الجامعة الإماراتية الدولية image/svg+xml المؤلف
  • Ahmed way Basic Science Departmen Higher Institute of Engineering and Technology, New Damietta 34517, Egypt المؤلف
  • Entsar H. Mater Department of Mechatronics, College of Engineering and Srnart Computing, Modern Specialized university, Sana'a 12544, Yemen المؤلف
  • Ahmed N. Al-Hakimi Department of Chemistry, College of Sciences, Qassim University, Qassim, Buraidah S14S2, Saudi Arabia المؤلف
  • Eman M. Abdallah Department of Basic Sciences, Delta University for Science and Technology, Gamasa, Mansoura, المؤلف
  • Maha Aiiad AleNzi Department of Physics, Faculty of Sciences-Arar, Northern Border University, PO Box 1321, 91431 Arar, Saudi Arabia المؤلف

DOI:

https://doi.org/10.1021/acsomega.5c04734

الملخص

This study presents a comprehensive investigation of the optical, thermal, structural, and electrical properties of poly(ethylene oxide) (PEO)/polyvinylpyrrolidone (PVP) blends embedded with molybdenum trioxide nanobelts (MoO3 NBs). The nanocomposites were fabricated via solution casting with varying concentrations of MoO3 NBs to assess their influence on the polymer matrix. X-ray diffraction (XRD) analysis demonstrated the semicrystalline nature of PEO/PVP blends and revealed structural modifications induced by the nanofiller. Fourier transform infrared (FTIR) spectroscopy showed electrostatic interactions between the polymer matrix and MoO3 NBs, facilitated by intermolecular and intramolecular hydrogen bonding. The indirect optical band gap decreased from 4.57 eV (pure blend) to 3.54 eV (4.0 wt % MoO3), indicating enhanced optoelectronic properties. Thermogravimetric analysis (TGA) confirmed improved thermal stability upon nanobelt addition, while scanning electron microscopy (SEM) revealed a uniform dispersion of MoO3 NBs within the polymer matrix. Furthermore, the nanocomposites exhibited significantly enhanced AC conductivity compared to the pure matrix, along with tunable dielectric properties consistent with non-Debye relaxation behavior. These findings highlight the potential of PEO/PVP-MoO3 nanocomposite samples as tailorable dielectric materials for advanced applications in flexible solid-polymer electrolytes and high-performance energy-storage systems.

 

السير الشخصية للمؤلفين

  • Eman M. Abdallah، Department of Basic Sciences. Delta University for Science and Technology, Gamesa. Mansoura. Egypt

     

  • Maha Aiiad Alenizi، Department of Physics. Faculty of Sciences-Arar. Northern Border University, P.O. Box 1321 , 91431 Arar. Saudi Arabia

     

  • Ghaleb M. Asnag، الجامعة الإماراتية الدولية

     

  • Ahmed way، Basic Science Departmen Higher Institute of Engineering and Technology, New Damietta 34517, Egypt

     

  • Entsar H. Mater، Department of Mechatronics, College of Engineering and Srnart Computing, Modern Specialized university, Sana'a 12544, Yemen

     

  • Ahmed N. Al-Hakimi، Department of Chemistry, College of Sciences, Qassim University, Qassim, Buraidah S14S2, Saudi Arabia

     

  • Eman M. Abdallah، Department of Basic Sciences, Delta University for Science and Technology, Gamasa, Mansoura,

     

  • Maha Aiiad AleNzi، Department of Physics, Faculty of Sciences-Arar, Northern Border University, PO Box 1321, 91431 Arar, Saudi Arabia

     

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α-MoO3 Nanobelts Boosted the Structural, Optical, Thermal, and Dielectric Properties of PEO/PVP Blends for Emerging Optoelectronic/Energy-Storage Applications

التنزيلات

منشور

2025-08-11

إصدار

2025

القسم

Articles

الفئات

الرخصة

الحقوق الفكرية (c) 2025 Copyright © 2025 The Authors. Published by American Chemical Society. This publication is licensed under

Creative Commons License

هذا العمل مرخص بموجب Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

كيفية الاقتباس

Abdallah, E. M., Alenizi, M. A., Asnag, G. M., way, A., Mater, E. H., Al-Hakimi, A. N., Abdallah, E. M., & AleNzi, M. A. (2025). α-MoO3 Nanobelts Boosted the Structural, Optical, Thermal, and Dielectric Properties of PEO/PVP Blends for Emerging Optoelectronic/Energy-Storage Applications. المستودع الرقمي الجامعة الإماراتية الدولية, 1(1). https://doi.org/10.1021/acsomega.5c04734

الأعمال الأكثر قراءة لنفس المؤلف/المؤلفين